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Calcium dinitrite

Calcium nitrite

CAS: 13780-06-8

Molecular Formula: CaN2O4

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Calcium dinitrite - Names and Identifiers

Name Calcium nitrite
Synonyms 237-424-2
CALCIUM NITRITE
Calcium nitrite
Calcium dinitrite
calcium dinitrite
Nitrousacid,calciumsalt
calcium nitrite solution
CALCIUM NITRITE ANHYDROUS
CalciumNitriteCa(NO3)2*4H2O
CAS 13780-06-8
EINECS 237-424-2
InChI InChI=1/Ca.HNO2/c;2-1-3/h;(H,2,3)/q+2;/p-1

Calcium dinitrite - Physico-chemical Properties

Molecular FormulaCaN2O4
Molar Mass132.09
Density2.23
Melting Point390 °C
Flash Point110°C
Water Solubilityslightly soluble alcohol [MER06]; g/100g solution H2O: 38.3 (0°C), 43.0 (18.5°C), 71.2 (91°C); solid phase Ca(NO2)2 · 4H2O (0°C, 18.5°C), Ca(NO2)2 ·2H2O (91°C) [KRU93]
Appearancewhite-yellow hexagonal crystals
Merck13,1688
Refractive Indexn20/D 1.3946
Physical and Chemical PropertiesThe pure product is colorless to light yellow hexagonal crystal, easy to deliquescence.
relative density 2.23
solubility soluble in water, slowly soluble in alcohol.
UseCan be used as the main raw material of concrete antifreeze, early strength agent, steel corrosion inhibitor

Calcium dinitrite - Risk and Safety

Safety DescriptionS23 - Do not breathe vapour.
S24/25 - Avoid contact with skin and eyes.
WGK Germany3

Calcium dinitrite - Upstream Downstream Industry

Raw MaterialsAmmonia
Calcium hydroxide
Calcium carbonate
Nitric acid
Nitrogen

Calcium dinitrite - Reference Information

LogP-2.52 at 20℃
EPA chemical substance information information provided by: ofmpeb.epa.gov (external link)
solubility in water (g/100ml) grams dissolved per 100ml of water at different temperatures (℃): 63.9g/0 ℃;84.5g/20 ℃;104g/30 ℃ 134g/60 ℃;151g/80 ℃;166g/90 ℃;178g/100 ℃
toxicity see sodium nitrite.
Application can be used as the main raw material of concrete anti-freezing agent, early strength agent and steel corrosion inhibitor
widely used in reinforced concrete engineering, used as cement hardening accelerator and anti-freezing rust inhibitor, the life of reinforced concrete structure can be increased by 15~20 years when 2% calcium nitrite is added to concrete. Corrosion inhibitors for the pharmaceutical industry, organic synthesis and lubricating oils.
production method industrial production mainly adopts milk of lime to absorb Nox to produce calcium nitrite, with continuous method and batch method. Continuous process is used to produce mixed gas containing 5%~ 0.5% NOx by discharging tail gas (containing NO + NO2 1.5% ~ 10%) in dilute nitric acid production process or by air oxidation of gas ammonia, the molar ratio of NO and NO2 is controlled to be about 1.5, and it is passed into the first-stage reactor at 40~70 ℃, and the mixture of gas and liquid is fully mixed and contacted, so that the milk of lime continuously absorbs Nox in the raw material gas, until the Nox content in the outlet gas is less than 1.5%, it is sent to the tower oxidizer, and ammonia gas is introduced to react with excess NO2 at 75~100 ℃ and 2~10kg/cm2 pressure, reduce the content of No2. In the secondary reactor, the primary neutralization liquid continues to absorb the tail gas of the primary reactor until the Nox content falls below 0.3%, and the pH value of the solution is controlled to be above 11, so that the secondary neutralization liquid contains 33.5% of calcium nitrite, which is filtered, the filtrate was concentrated by evaporation, cooled to crystallize, centrifuged and dried to obtain a calcium nitrite product. Ca(OH)2 + NO + NO2 → Ca(NO2)2 · H2O
Last Update:2024-04-09 19:05:07
Calcium dinitrite
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Hefei TNJ Chemical Industry Co.,Ltd.
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Tel: 0086-551-65418684
Email: sales@tnjchem.com
     info@tnjchem.com
Mobile: 0086 189 4982 3763
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Zouping Mingxing Chemical Co., Ltd.
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Email: xuli678323@126.com
Mobile: +86-13605431940
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View History
Calcium dinitrite
METHALLYL METHACRYLATE
Raw Materials for Calcium dinitrite
Ammonia
Calcium hydroxide
Calcium carbonate
Nitric acid
Nitrogen
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